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Kassandra first. Going off only what we have seen from E3 gameplay Alexios' voice is a bit cheesy and forced sounding. Much of the dialogue seems cheesy to begin with so it may not be the voice actors fault. Kassandra might not be very historically accurate but they seem to be leaning away from that anyways.
Never played AC Odyssey, so this talk about Kassandra versus Alexios, and Kassandra being a so much better character, always confuses me. Aren't their story and lines the exact same? So the voice actor of Kassandra does just a way better job than that of Alexios? yep, exact same. Difference is .